Guerrilla guide to CNC machining

Benchtop manufacturing tips, thoughts, and recipes for robot builders, model makers, and other hobbyists

VOLUME I: Basic theory and preparations

Copyright (C) 2007, 2008, 2009 by Michal Zalewski <lcamtuf@coredump.cx>

1. About the series

The craft of robotics, like many other precision engineering hobbies, seems to require either remarkably deep pockets, or a combination of outstanding manual skills, lots of patience, and unrestricted access to a well-equipped metal shop. Unfortunately, these options are not universally accessible to urban-dwelling part-time do-it-yourself builders. Because of this, many of otherwise talented folks seem to either give up, or resort to overly simplified (and still pricey!) premade kits, or to junkyard quality engineering.

Much of the time, it seems, the most basic tasks prove most challenging. Making a simple joint, a custom gearwheel, or a cover of desired shape, is beyond the realm of imagination for many of my colleagues, whereas sophisticated sensors or advanced microcontrollers and data interfaces are easy for them to employ and hook up to desktop computers in no time. Given that computer numerical control milling, a technology capable of addressing this root problem is now affordable and home setup friendly, it really does not have to be this way.

This is a guide to the technology in question. The use of CNC mills in industrial applications is well-studied and extensively documented, and remains one of the staple processes of large-scale manufacturing. Unfortunately, the workflows, materials, and tools most commonly employed in amateur small-scale work are largely a gray area, with no comprehensive and useful reference materials to be found anywhere.

I took a leap of faith, and had to learn small-scale CNC manufacturing the hard way. I invested a good chunk of money to set things up without any sort of an assurance it would actually work the way I hoped, then spent months on trial-and-error experiments. I came up with some good ideas and plenty bad ones, and had to bear with easily avoidable frustrations and annoyances. It was well worth it, to be sure: two years later, I can use a great tool with confidence, and get results that routinely surpass my expectations. I do not see a reason why it has to be this hard for others, though - so, the purpose of this guide is to organize all the information I managed to find to date - first setting up a shop in Europe, and then relocating to the States later on. My hope is that it will help you decide whether CNC milling is right for you, and give you the head start needed.

The guide assumes no specific formal background in materials science, mechanical engineering, or electronics; if you have some, you might be tempted to skip parts of it, or just have a hearty laugh here and there. If you want to learn about mechanical engineering, one great book recommended to me is "Mechanical Engineering Design" by Shingley et al; it is thick, dense, and pricey ($70-$150, depending on edition) - but will give you the exact math and practical considerations behind everything from springs to gearwheels. For a more hands-on approach to various mechanisms, with less focus on material science calculations, "Machine Devices and Components Illustrated Sourcebook" by Parmey ($65) and "Mechanisms and Mechanical Devices Sourcebook" by Sclater and Chironis ($70) are good choices. And if you want to explore electronics, "The Art of Electronics" by Horowitz ($75) is the way to go.

As for this guide - volume I explains what CNC machining may do for you, and how to set up a decent workshop for amateur engineering jobs. Volume II, due later this year, will outline practical CAD/CAM workflows and engineering tips for working on real-world projects; and volume III is meant to be a collection of specific design recipes based on my experience to date.

Oh, and just to set the record straight: I am your typical, random IT geek secretly in love with amateur robotics. I claim no particular expertise or authority in this field. In lieu of credentials, several photos of my robot designs to date can be seen here.

2. Milling? That's so old school!

Computer numerical control milling is a subtractive method for processing raw material with a drill-like rotating cutter - an end mill - through a set of computer driven movements of the table or the tool itself in multiple axes. Some of the most basic designs at first sight resemble just a press drill on steroids - unwieldy, noisy, boring, and outdated. To many people I chatted with, the future of home manufacturing seems to be with several exciting additive technologies, such as 3D printing (also known as fused deposition modeling, and featured on Slashdot every other week), stereolithography, or selective laser sintering, all of which work by arranging and binding subsequent 2D layers of material until a desired 3D shape is built from scratch - and not with something nearly as boring as a mill.

In reality, however, these technologies are still largely impractical for affordable general-purpose manufacturing, and will probably remain so for the next ten or fifteen years, pending several technological breakthroughs; the exact timeframe is subject to a debate, but the promise of the next manufacturing revolution is in the air for as long as I remember. CNC milling, on the other hand, by the virtue of its simplicity, got greatly and tangibly refined in the past two decades, and had now entered the benchtop domain with a broad selection of hobbyist-friendly designs. It also remained a foundation of manufacturing processes through the world, used to produce plastic injection and thermoforming molds, sheet metal stamping tools, and to directly process a vast number of other materials.

As of now, the main advantages of computerized subtractive prototyping for home workshops are: On most counts, CNC trumps additive technologies - but to be fair, there is also a caveat: most additive technologies are capable of producing complex internal geometries (for example, a mostly enclosed sphere with sophisticated internal features), as long as all the geometry is properly attached and supported through the manufacturing process. The task is not simple, to be sure - the design and removal of support structures is time-consuming and error prone by itself - but the goal as such is attainable. CNC mills, on the other hand, cannot machine hidden features if no appropriate clearance for the cutter is present from any angle.

This limitation introduces some overhead and sometimes requires a bit of creativity to split parts into pieces that will be machined separately, and then joined together in a manner suitable for the application in question - but if you look closely, almost all the high-tech products seen in our households were engineered to work around this caveat, from toy cars to portable computers. There are very few cases when you really need to make a non-openable, sealed bag with a non-removable cat readily in it.

All right, let's go through the process of setting up a workshop for CNC milling. This serves as a good opportunity to discuss some of the associated features, options, costs, and other dirty secrets of this technology.

3. Selecting the right mill

General purpose benchtop sized CNC mills start at slightly over $1,000, and go up to $30,000 or so. Surprisingly, even the cheapest mill will suffice for most jobs (certainly for the processes advocated in this guide). If you are not a fan of bare-bone setups, still - no matter how picky you decide to be, you can likely get all the essential features under about $5,000. Past this point, you pay mostly for convenience and specialty options such as automated tool changers and closed loop control motors for unattended processes, speed, power, and rigidity improvements for better metal machining performance, larger working areas for grand scale projects, and so forth - all of which are nice (and sometimes handy), but seldom truly necessary in hobbyist workshops.

There are numerous benchtop CNC mill manufacturers around the world, selling both dedicated setups, as well as quality manual mills that may be optionally fitted with motors. One of the best known and reputable international brands aimed at small-scale manufacturing and selling dedicated CNC units is Roland; for retrofits, most users turn to Sherline and Taig. That said, it makes sense to explore local markets. For example, in the States, MaxNC, Flashcut, MicroKinetics, and CNC Masters all offer affordable designs; in Canada, there is Charlyrobot; in Japan, there is Mimaki; Germany has BZT and Max Computer. In Poland, JAWO offers competitively priced mills. Use search engines, look around, ask questions.

Several hobbyist communities (say, CNC Zone) aim to build do-it-yourself CNC mills. Results posted by their members range from wobbly "plywood frame with Dremel tool taped on" curiosities to some impressively high quality designs. If you are a determined and skilled engineer with a good access to CNC machining facilities in the first place (oops!), you might choose to pursue this route. Be warned, however, that this is a painstaking and time-consuming effort, and the decision is very unlikely to be economically sound: the prices of quality components such as ball screws and other linear motion systems, powerful low-backlash servo motors, and the like, are fairly high - and on top of this, you will almost certainly have to iterate through several designs before coming up with the one that actually works well for you.

For non-DIY shoppers, there are virtually no meaningful comparisons of small, commercially available CNC mills (the one page I knew about, DesktopCNC.com, went dead in 2007, and seemed to be inaccurate and outdated in some aspects anyway). More importantly, some manufacturers do their best to make direct comparisons hard by coming up with useless or irrelevant metrics or test methodologies, and conveniently skipping some less flattering benchmarks; as such, picking the right option will involve going through a number of specification sheets, trying to make sense out of the information therein, and perhaps pinging the vendor to learn more. To help you out, here's my list of the parameters you will likely encounter, and some tips or thoughts on their importance.

Let's begin with important characteristics that vary significantly from one machine to another (and if not specified, are worth inquiring about): Now, moving on - parameters that matter less, or are unlikely to vary significantly: Well, that is all. The list could probably go on, but this covers all the reasonably common, and not necessarily obvious characteristics to take into account when making up your mind. If you care, I used to have Roland MDX-15, an entry-level mill priced at about $1,700; and then switched to Roland MDX-540, which is an upper shelf variant. I liked MDX-15 a lot, and I am deeply in love with the latter unit, too. But really, there are many good options to choose from.

A final good tip is to find the actual PDF instruction manual for your mill of choice before you make the final call. These are often either available for download from manufacturer's website, or may be bootlegged somewhere; if not, you can often talk resellers or existing users into giving you a copy. Manuals let you get a good grip of how it feels to operate the unit and what additional limitations it might have.

In most cases, once you order the machine, you will have to wait a couple of weeks for it to be manufactured and shipped to you; relatively few models are in continuous stock. This is actually pretty good, however, as it gives you time to shop for tools, software, cutters, and machinable media, so that you can unwrap the device and start having fun right away - instead of staring blankly at the device once you unpack it, then getting discouraged by rushed experiments.

4. 3D CAD software

The mill itself aside, the only other potentially significant expense you will encounter is all the specialized software. The first application you need is a computer aided design (CAD) tool to draw your desired parts as 3D shapes and manipulate them as needed.

In principle, it is possible to rely on just about any general-purpose 3D drawing program - such as the free of charge, open source Blender, or moderately expensive and easily available Lightwave or 3d Studio max. In fact, you might very well start with these if so desired - although you must expect some annoyances. General-purpose 3D software usually focuses on manipulating polygon-based shapes, shading, and animating them as needed. These applications often support highly configurable renderers, physics systems to model explosions, and so forth - but offer you relatively few tools to make sure that parts are aligned to a specified precision, that imperceptible inaccuracies do not stack up with every subsequent operation, that surfaces are perfectly even, that geometries are error-free, and so on.

Specialized 3D CAD utilities, on the other hand, ditch most of the eye candy, and focus on providing extensive support for convenient and highly accurate technical drawing primitives such as NURBS objects, offer a number of useful procedural drawing functions, have tools for orienting and aligning objects very precisely in a large number of ways, and provide methods for accurate shape extraction and modification. They also offer engineering-oriented measurement and analysis tools.

In other words, you may get started in any 3D application - but eventually, you might be tempted to get proper tools for the job. Luckily, there are relatively few catches attached: there is a boatload of CAD applications for you to try out, and the primary factor is just how well they handle for you. Try as many as possible (some are free, some cost from $100 upward, and most have free trials), and make up your mind. You might want to search around, or just start with a page such as this list of tools.

Simply look around and pick whichever user interface you find most useful and responsive - but be warned that one of the most important secrets of CAD design is that no matter how complex is the part you want to make, you never should be building it by visual approximation, dragging primitives with your mouse until they "kind of" fit together. Clean and maintainable models should never have any unnecessary, intersecting, hidden parts or unintended and unpredictable inaccuracies. All CAD applications feature a sophisticated array of object snaps, parametric manipulation functions, and trimming features that enable you to get things perfectly right, right away - and for every product you are considering at this point, you need to figure out how to get to these functions, and how intuitive they are. Read manuals, go through tutorials, and try to make something reasonably simple, such as a mock gearwheel with wacky teeth. If you can get there without having the urge to throw your computer out the window, this is a good sign already.

If you do not want to go through all this trial and error, a program by which many CNC users swear by is Rhinoceros. It is very likely the last CAD program you will ever need, and you are very unlikely to be disappointed. It is somewhat on the pricey side ($900 for mere mortals, $150 if you are a student or know one) - but it's worth it. It is very lightweight, responsive, and not resource-hungry, yet offers an impressive array of features that will have you all set for the foreseeable future. If you can afford it, you can just buy it right away. Otherwise, keep on looking.

5. 3D CAM software

A computer-aided manufacturing (CAM) application needs to be used to convert 3D shapes (polygon meshes or NURBS-based objects) into actual tool movement commands (toolpaths) to be sent to the machine. Although the choice of a CAD tool used to design your parts is mostly a matter of personal preference, CAM applications tend to differ in important and sneaky ways. Making the right choice is hard - and making the wrong one may prevent you from using your machine optimally and reliably.

Almost every machine on the market will typically come with some CAM software bundled, and depending on the make, the software may be reasonably useful; for example, Roland Modela 4 is a pretty good CAM application; on the other hand, its successor, SRP Player, is unfortunately more crippled. You might want to check what you will be getting, and ask nicely a copy of user's manual or an installation binary beforehand. In case the bundled program turns out to be a dud, do not despair - there are some good, basic programs available free-of-charge (e.g., FreeMill), or for a relatively low price ($100 for StlWork2, $300 for DeskProto Lite). The only caveat is, these low-cost applications will usually not support obscure, proprietary communication protocols - which is why, again, it is important to get a device that talks standard G-code or other commonly recognized dialect.

That said, all the free or low-cost programs are noticeably limited, in one way or another. They might be perfect for some tasks - but other jobs will be very painful to set up, or just needlessly time-consuming to run. Most of these applications do not support features such as 4-axis milling, do not offer the ability to restrict cutting to hand-drawn regions, and do not offer a decent level of control over toolpath generation strategies. Some will also generate badly suboptimal paths under some circumstances - for example, by not keeping track of the material already removed in previous passes, not being able to vary cutting speeds depending on anticipated chip loads, or not grouping operations by their relative proximity.

And quite unfortunately, molds and mechanical parts tend to be pretty complex. This means that sooner or later, you will be very likely tempted to upgrade to a fully-featured application. There are several very competent CAM programs that offer all the tools needed and then some - but regrettably, the authors of many of these applications still live in the era of all CNC machines weighing a ton and costing $80,000 or more. In some cases, their pricing reflects the desire to cash on industrial uses, and makes no provisions for the emerging market of serious amateurs.

So, many of the fully featured programs are priced in the $1,000-$3,500 range. Hefty student discounts are a norm (80-90% off), so if you are a student or know one, this is a very good option. Otherwise, you might try to bargain / reason with vendors (most of these companies are relatively small shops and may cave in to popular demand). You can also shell out the money, of course, but it just does not feel right to need $3,000 in software to operate a $1,500 mill. Bah.

Shop around, try to find good deals, and examine lower cost "lite" versions for the features you might have an use for; some of the more important options you might want to have in your CAM package include: Oh well. Quite a list, eh? But that's pretty much it.

As mentioned through the text, some of the popular vendors of better featured general-purpose CAM applications include DeskProto, Mayka, VisualMILL / RhinoCAM, Mastercam Mill, madCAM, and quite a few more; search around, grab evaluation versions, and toy with them as much as possible.

Based on my experience with evaluation versions of these apps, I would recommend VisualMILL and Mayka the most. VisualMILL has an excellent choice of toolpath strategies, generates toolpaths quickly, and can perform arc interpolation - but has some minor glitches here and there. Mayka has a responsive UI and very few bugs; it is, however, slow with some toolpaths and has inferior region selection capabilities. On the subject of bugs, I advise against DeskProto, primarily because of odd limitations and erratic toolpaths I encountered.

Of recent, Roland introduced their own rather pricey software, SRP Player Pro, to go with many of their milling machines. I looked at their detailed usage tutorial posted on the web, and it seems to be behind VisualMILL on many counts - but maybe isn't.

6. Buying cutters

There is a vast selection of end mills available from multiple manufacturers, and navigating the catalogs might be somewhat overwhelming. Given that many of them are priced in the $10-$40 range, you can afford to make some mistakes, but making too many of them will simply hold you back on making the parts you want.

For starters, this illustration outlines the anatomy of a typical cutter:
                .----------------------- total length ------------------------.
                |                                                             |
                                                               .- cut length -|
                                                               |              |
            _    __________________________
           |    |                          \                       
     shank |    |                           --------------------~~~~~~~~~~~~~~.    -.
  diameter |    |                                                \ \ \ \ \ \ \|     | cutting diameter
           |    |                           --------------------~~~~~~~~~~~~~~'    -'
           |_   |__________________________/                                  `------ n flutes (helix)
                                                                                      angle specified
                                            |                                 |
                                            `--------- reach length ----------'
Some of the defining qualities of modern end mills are: Various other fancy features can be seen on some cutters: coolant holes, chip breaker patterns (roughing mills), variable helix angles, and more. Neither of these are particularly useful within the scope of this guide, though. Vanilla mills typically cataloged as finishing cutters are optimal for all precision processes.

There are quite a few end mill makers around the world. Some of the most reputable names, with best selection of precision mold machining tools, include Hanita and, somewhat more local to Europe, Nachreiner. Hanita products are distributed in the States by regional Kennametal representatives (just look up your state, and give them a call); there are multiple distributors in Europe, and I had best experience to date with Industrial Tooling Corporation. They have extensive stocks, superb customer service, and ship cheaply and promptly (by comparison, our local representatives had me waiting several months on a single order once). Nachreiner also has a network of representatives in many parts of the world, although my experience here is limited to Matbor - unlike Hanita reps, they are OK, so I had no reason to look elsewhere.

In addition, in the States and some other parts of the world, there is a fair number of other brands to choose from; US examples include Cobra Carbide and Harvey Tool. In my experience, Cobra Carbide has a spectacularly poor customer service, but a great selection of quality basic end mills at very competitive prices. Harvey Tool looks good, but is on the pricey end - and I had no direct experience with them. Lastly, MSC Direct carries a decent selection of mills from several manufacturers.

In the States, there is a somewhat greater selection of imperial size cutters, compared to metric - but this is, thankfully, changing. I would generally advise against using imperial measures for precision work, as it quickly gets weird and cumbersome (unless you just love converting 3/64 to decimal fraction and back); but I am a metric system native, and so YMMV.

Catalogs of said manufacturers can be found here: A barebone set of cutters for working in plastics might be: Depending on the projects you plan to be working on, you might also want to consider: Wood and metal work might benefit from a different set - but for most intents and purposes, you should be off for a good start with this selection. When browsing through the end mill catalogs, you might feel like a kid in a candy store - but do not be tempted to get one cutter of each variety just to "try it out". For almost all materials, 4 and 2 flutes, low / normal helix, TiAlN cutters of standard geometries are best, and these probably occupy 3 pages or so in a typical catalog. For aluminium, wood, rubber, low helix angles and fewer flutes are better, and these will have their own page, too.

Once you have a set of cutters decided upon and ordered, it is important to revisit the topic of cutter mounting options - and order the necessary tool collets for shank diameters you intend to use. Standard collet manufacturers are easy to find, so just Google around. As noted earlier, my source of choice in the States is Techniks USA - they have affordable ultra precision ER16 collets, and ship quickly. As a general recommendation, it is advisable to buy collets with a lower end of the accepted tool diameter range matching the tool you intend to use (for example, 3 mm tool should have a 3.0 - 4.0 mm collet), as this results in improved accuracy.

When working in prototyping materials with precision cutters, one collet is likely to last pretty much forever, unless you manage to mount them improperly (which is pretty hard, but some people manage to pull that out); so, no need to stock up - get one of each size you want.

7. Getting stock material

Milling machines are not fussy, and will cut almost anything that is rigid enough to stay in place, and softer than the tool itself. Still, some materials produce better results than others. Some of the canonical examples of materials that are worth machining include rigid polyurethanes (PU), epoxies, and polyesters; acrylic glass (demanding by the virtue of being prone to stress cracking - but doable); a variety of hard woods, such as cherry, maple, oak, pear, apple, jatoba; aluminium, brass, and other softer metals and alloys; plaster; hard waxes; PCBs; and quite a few more examples of lesser importance to robotics.

Examples of common materials that machine with greater difficulty or to lower quality finish include malleable thermoplastics, such as polyethylene terephthalate (PET), polycarbonate (PC), polyvinyl chloride (PVC); rubber and other elastomers, unless frozen; typical varieties of plywood; expanded and extruded polystyrene foams; iron, ferrous steels, and other hard alloys; stone and glass. Now, do not get discouraged - materials that do not machine well can be still be processed using a CNC mill, just not directly; for example, rubber can be cast from a liquid resin using a machined mold, while thermoplastics, sheet metal, or even wet paper, can be stamped using a two-part die.

Of all the directly usable materials, because of superb machinability and a wide variety of favorable mechanical properties, rigid polyurethanes and epoxies are a primary choice for almost all prototyping work - that is, unless you specifically need to take advantage of thermal resistance of metals, or aesthetic qualities of wood. You can buy various blocks of CNC media based on these plastics. Air or syntactic foams, solid blocks of polymer, or mineral-filled systems to cheaply simulate a broad range of other materials, are available alike. Brand names include Precision Board products (from Coastal Enterprises, US-only), RenShape (from Huntsman, available worldwide), Necuron (from Necumer, sold mostly in Europe), several lines of Axson products (worldwide), Sanmodur (from Sanyo Chemical, common in Japan), and more. Said brands are distributed through a number of resellers, although unfortunately, not all of them advertise or let you browse their inventories on the web - so e-mailing or giving a call to the manufacturer is often the best way to find out more.

One reseller I had an excellent experience with is Walco Materials; another web-friendly place is Freeman Manufacturing and Supply. In Poland, Milar is a good source, and in the United Kingdom, Mould Life might be a decent pick, too.

If you browse manufacturers' catalogs for prototyping boards, you will likely be overwhelmed - there will be boards of various hardness, abrasion resistance, temperature resistance, thermal conductivity, and so forth; but don't panic - you do not need to make any tough choices. The best option is to get a single, common variety of a board that can be machined quickly and cheaply to achieve high quality surface finish; and then to use a resin casting process to replicate machined shapes in anything from floppy rubbers to bullet-stopping fiber plastic composites.

At first sight, the process of making molds and casting parts using liquid resins appears to be an overkill if you do not intend to start a production line - a more intuitive choice is to just carve the item you need from the prototyping board itself. Upon closer inspection, several reasons why this is not a great idea become apparent, though. Firstly, casting means far better efficiency and lower costs. Machinable media comes in blocks of predefined size, and you will seldom have a block exactly matching the envelope of each and every part you ever want to make (not to mention, even if you had, securing it to the mill would not be trivial), so you would end up having to remove and discard a vast majority of a workpiece every time you need to make a single copy of even the smallest part. Making a mold, on the other hand, requires much less material to be removed, and often allows the remaining block to be resurfaced and reused; plus, you are free to make as many copies of a machined part as deemed necessary, without any further waste, tool wear, dust, or noise concerns.

Casting also gives you convenient access to a variety of materials without having to experiment with challenging cutting processes, or wearing out your cutters. You can make parts from a vast range of liquid resins, and several other materials, without having to worry how tricky to machine they might be, and what parameters need to be used to prevent tool breakage or other problems. You always get to work in the same, well-tested media, even if the final part will be made from concrete mixed with gravel and barbed wire.

Finally, with casting, you gain the ability to make duplicate parts very easily - including tweaking their mechanical properties following failed experiments, or using different dyes to find pleasing colors. No need to redo the cutting.

To get started with the process, you need a 25 or 50 mm thick, medium density prototyping board, such as Coastal Enterprises PBLT-48, Huntsman RenShape BM 5460 or 460, Necumer Necuron 640, or Axson ProLab 65; these boards trade for about $5-10 per kg, at a density of about 0.6-0.7 g/cm³, and in volumes of 15 to 30 l (a common size is 1500 x 500 x 25 mm). Smaller packages are possible to find, but are grossly overpriced - and given that the material is used up rather quickly, it does not make sense to take this route unless you are on a very tight budget. Boards in this range resemble wood, are non-abrasive, fairly lightweight, robust, and can be easily cut with a jigsaw. They can be also machined at amazing speeds and produce relatively little volatile dust. Multiple slabs can be seamlessly glued together to make larger workpieces, too. Although some folks try to keep costs down by starting with other media, in my experience, it's not worth the effort.

An optional accessory you might want to consider are epoxy or polyester putties that can be used to repair incorrectly cut areas and have them re-machined without throwing away the entire block (or to glue together multiple boards or board fragments to construct a larger workpiece); one such putty is Freeman's Quik-Fil, but a wide variety of alternatives exist. The putty costs about as much as the board, kg-per-kg, but it often leads to significant savings - because as little as 5 g will sometimes serve to rescue a large and complex mold that took a good chunk of a prototyping board and several hours to machine. Getting about 1 kg of the putty is not a bad idea. The polyester variety has a fairly strong smell and is flammable, but cures very quickly and costs less; epoxies are slower and more expensive, but more user-friendly. Your call.

Oh, there is one downside of medium-density prototyping boards that you should know about: they do have a subtle grain that yields a slightly matte finish when casting transparent resins. Naturally, final parts made out of hard plastics can be polished to high gloss manually, painted over with a clear coat lacquer, or put in a tumbler - but it takes some effort and affects dimensional accuracy; plus, the trick does not work well for elastic, rubber-like elements. Another option is to apply and carefully buff wax paste or a similar sealant to close all the pores before using the mold; this is a very good option for smooth and simple shapes, but might be difficult for molds with tons of fine detail. When neither of these methods is acceptable, an alternative approach is to make the mold using denser epoxy or polyurethane tooling boards that, when machined right, yield a smooth, shiny finishes without the need for extensive postprocessing. For Huntsman, RenShape 5169 (BM 5272 in Europe) is a good choice in this category; many but not all competitors offer similar products - Necuron 1001 and Axson LAB 850 seem similar, too. These materials may be around 30-50% more expensive, and need to be machined 20-40% slower, than the boards mentioned earlier, however. Do not buy such a board right away, and definitely not as your primary machining material - but be aware of the possibility.

When you have the board... well, the next step depends on the material you want the final part to be made of. For rigid polymers, for example, the usual process is to cut a positive in polyurethane prototyping board, then produce a negative form with an appropriate silicone resin, and then cast the final part using this mold and an appropriate resin. Since silicone does not stick to polyurethane and other plastics, only minimal material surface preparation is needed, and there are very few things that could go wrong; and because the intermediate mold is flexible, demolding the final rigid part is very easy.

This demonstrates a minimalistic process with single-side molds:
          .- silicone poured in                                                    .- polyurethane poured in
          |                                                                        |
  __      v     __                         __________                              v
  ::|    __    |::                        |@@@@@@@@@@|         rotate          ___    ___                          ___
  ::|___/##|___|::           ->           |@@@/  |@@@|           ->           |@@@|__/@@@|           ->           |##/  
  ::::::::::::::::                                                            |@@@@@@@@@@|
      
  Positive form (PU)               Negative cast (silicone)                                                       Final part (PU)
Many types of elastic parts can be cast directly using negative rigid molds; and more complex, multi-sided forms (e.g. two halves) can be made where necessary, too, with proper holes and pins for perfect alignment and easy pouring of the liquid material. I will go through some examples later on.

Casting chemistry is available from a number of manufacturers, fairly inexpensive, and - as discussed later - reasonably safe. You will need some additional equipment to make high-quality castings, but nothing excessive: a box of single-use containers, pads, syringes, and a set of large needles (available from veterinary supply stores); a reasonably precise weighing scale; plus, preferably, a small vacuum pump to evacuate dissolved gases and trapped air bubbles from resins. We will discuss all these shortly.

7.1. Silicone rubbers for molds

Silicone rubbers are one of the most hobbyist-friendly polymers available. They combine easy and safe polymerization with very good mechanical properties, such as high tensile and tear strength, dimensional stability, chemical resistance, or flawless temperature resistance up to at least 200° C. They are an excellent material for very accurate, flexible die molds, but can be also used to make final parts such as tires, pads, transmission belts, and more.

All silicone rubbers are based on a class of organic silicone compounds, siloxanes. In presence of proper agents, siloxanes polymerize - but depending on the exact composition, there are several ways this process can be triggered. One-component, room-temperature polymerizing rubbers (RTV-1), commonly employed as sealants, simply respond to air moisture - but they are of little use in mold making, as they are difficult to work with, cure very slowly in thicker layers, tend to have fairly obnoxious smell, and may remain somewhat corrosive to metals due to acidic residues produced during polymerization (though some non-corrosive compositions are available, too). Another category, high temperature polymerizing compositions (HTV), responds to peroxide reactions at elevated temperatures; needless to say, this is also fairly cumbersome for hobbyist applications.

The two types of two-component, room-temperature polymerizing rubbers (RTV-2) of interest to mold making are: The choice between condensation cure and addition cure compositions is largely a matter of personal preference. Addition cure rubbers are at least about 25% more expensive, but I find them much more fun to work with.

When choosing a silicone resin to use, the type of cure aside, there are several parameters to look for: Other parameters are of less significance, or are not expected to vary much between products within a particular class.

There are several makers of mold making silicones; in Europe, ACC Silicones has definitely the most interesting range, and I had great success using their products. In the States, these products are marketed as Quantum Silicones - but unfortunately, my adventures with Quantum's impressively unresponsive customer service discouraged me from purchasing from them. That aside, ShinEtsu sells several very interesting formulations; Bluestar Silicones (formerly Rhodia) has a nice array of products available globally, although they do look pale compared to ACC; Huntsman and Axson also carry a modest selection of RTV-2 silicones, but nothing of note. Local manufacturers in the States include Polytek, GT Products, or Silicones Inc.

On the US market, Freeman Mfg & Supply is a distributor for Bluestar Silicones; Walco Materials carries several brands, including ShinEtsu. In the United Kingdom, Mould Life seems to have some interesting custom products, although again, I don't have any first-hand experiences with that last company.

My top recommendation for an addition cure mold making silicone for people in Europe is ACC Silicones MM 242. It is a strong, food-grade, hard (40 Shore A) rubber with very low viscosity (~10,000 mPa*s), and long pot life. It is translucent and easily pigmentable, and tolerates silicone oil dilutions up to 70% by weight, to go to super-soft rubbers and extremely low viscosities where necessary. It has a fairly weak polyurethane resistance, limiting mold life somewhat - but nothing drastic. Alternatively, if you want to invest into a vacuum degassing rig ($200 or so), ShinEtsu KE 1310ST is another excellent, nearly transparent resin with excellent polyurethane resistance; it is too viscuous to use without a vacuum chamber in complex molds, but its relatively high transparency makes up for all the inconvenience.

Non-vacuum users in the States may consider Quantum Silicones QM 237, which seems to be a rough equivalent of MM 242; as mentioned, I wasn't able to actually order it in a timely manner and a sane quantity, but you might have more luck. Other than QM 237, I am yet to find a comparable alternative on this market. Polytek PlatSil 71-40 is a transparent resin with more than twice the viscosity, but may still work well - never tried it. Rhodia / Bluestar V-340 + CA-45 or CA-55 catalysts (44 and 45 Shore A, respectively) is a comparable opaque formulation, too.

Well, that's it. Typical prices on silicones hover around around $25-$40 per kg (addition cure falls closer to the upper end of this range). Their suggested shelf life is typically about a year, but if you store them in proper conditions (tightly closed containers, around 20° C), you can safely assume at least 2-3 years with no significant deterioration; the primary risk is that when stored in excessive temperature or if exposed to fresh air or UV radiation, they may slowly polymerize.

It makes sense to get at least about 4 kg to begin with - you will burn through it quickly during initial experimentation. If you want to experiment with softer parts and opted for addition cure compositions, you might get some 50 mPa*s silicone oil to go with the purchase, too (1 kg will do!). Silicone oil is also a pretty good lubricant for mechanical parts, or as an agent for sanding and polishing, and costs next to nothing.

NOTE: Most resin manufacturers in the States use a somewhat confusing approach when describing the size of their 2-component resin kits; "1 gallon kit" usually means 1 gallon of whichever component is needed in larger quantity, plus an appropriate amount of the other component. For a resin with a 10:1 mix ratio, this means you are buying around 1.1 gal, so the error is minimal; but if the ratio is 80:100, you are likely getting 1.8 gal instead. Be sure to account for this when comparing prices - quite often, more expensive "1 gallon" kits are actually a better value.

7.2. Polyurethane elastomers

Silicones are one of the best synthetic rubbers available to hobbyists, and an excellent choice for almost all flexible molds. Their two main weaknesses are the relatively high price, and the fact that the high tear varieties that are reasonably easy to pour into a form end at around 50 Shore A (there are several 60-70 Shore A compositions, but either at unbearable viscosities of 100,000 mPa*s or more, or with poor tensile parameters). In almost all cases, 40-50 Shore A is more than enough for typical molds, production of some final parts such as thin and small transmission belts, tough tires, or some load bearing dampening pads, could benefit from extra stiffness; for reference, car tires and soles are closer to 80 Shore A.

There are quite a few other types of synthetic rubbers, but most of them are not very convenient to make at home, or have other fatal flaws. Polyurethane elastomers are an important exception. These rubbers easily go up to 90 Shore A while maintaining good elasticity, are readily available as liquid prototyping resins, and compared to silicone, remain very easy to pour (1000-4000 mPa*s is common); most compositions are also some 25% to 50% cheaper than addition cure silicones.

On almost all other counts, they are a less exciting material, to be sure: they bind to many substrates and hence require demolding agents (though it is an advantage when you want to glue your rubber parts to each other or to something else), the chemistry is a bit more messy, their elasticity and rebound characteristics are usually worse, and temperature resistance is weak (80° C or so is enough to soften them significantly). You do not strictly need to buy any polyurethane rubbers for your initial setup, but you will probably have an use for them at some point - to cast rubber-like parts, as a surface coating for rigid parts, or as a material for particularly challenging molds.

Relevant parameters to look for in these compositions are similar to these of silicone rubbers; hardness range of 60-90 Shore A probably makes most sense (60 resembles a bouncy ball; 90 is closer to a rubber mallet used in sheet metal work, and will be flexible only in relatively thin layers - but can be, to some extent, machined and polished). Pot life will be typically shorter (10-20 minutes - stay away from compositions that give you much less), and flow characteristics different, so look for mixed viscosities under 4,000 mPa*s for convenient operation (around or under 1,500 mPa*s is best). Make sure the product you are looking at is reasonably flexible - there should be a decent tensile strength specified (at least 6-15 MPa for said hardness range), elongation at break should be reasonably high, and no flexural strength should be given (if there is one, this would imply that a sample specimen breaks when bent). Our crude stiffness ratio should fall within the under 0.8 or so, and shrinkage should be under 0.3%. Check that the list of recommended applications explicitly mentions "rubber-like prototyping parts" or "flexible molds", too.

In Europe, the choice was somewhat underwhelming; Huntsman had a nice line dubbed RenCast 6414 with moderate humidity sensitivity and good cure profile; but it was getting phased out as I was moving to the States, and had a caramel color that made it difficult to pigment it any color other than black, beige, or such. Axson offered a broad range of low-toxicity rubbers such as UR 3450, but likewise, seem not pigmentable. The selection on that market may have improved in 2009 - if you know more, let me know.

In the States, on the other hand, the picture is more rosy; Innovative Polymers has an impressive range of elastomers, including clear and easily pigmentable ones: IE-70A is a relatively cheap, pigmentable white rubber that has a somewhat wonky cure profile (may not cure well on surfaces exposed to air, or if heated up too quickly), and IE-9070 is a more pricey, transparent, vaguely straw-colored polyurea that is very easy to work with; Freeman sells their own range of elastomers such as 1040 (neutral white) and 1050 (transparent pink), but both are mercury-catalyzed; finally, Huntsman sells RenCast 6401-1, a composition that seems identical to IE-70A, but - again - with a mercury catalyst.

Since you will be making only a limited set of final parts from this material, your uptake will be relatively low - shop accordingly. Typical advertised shelf lives on these compositions span between 1 and 2 years, but as with silicones, you can easily exceed them with no ill effects - they are pretty stable, unless overheated, or exposed to moisture, fresh air, or excess sunlight. The price should be around $20-$30 per kg.

Important: some advanced rubbers without mercury catalysts, such as two completely transparent compositions from Innovative Polymers - IE-70AC and OC-50xx - may be inhibited by platinum catalysts used in polyaddition silicones. Check datasheets carefully to avoid trouble, unless you opted for condensation cure silicones instead.

7.3. Rigid polyurethanes

A-ha! Rigid polyurethanes are one of the sexiest, most useful plastics you can cast at home. An impressive selection of PU resins is available on the market, mimicking just about any other common plastic. Formulations with excellent impact resistance, flexibility, hardness, abrasion resistance, and desired visual qualities (transparent / easily pigmentable) are available.

Some of the parameters defining these materials are: Other parameters are usually not consistently provided by all manufacturers (e.g. impact strength is not commonly assessed), or are less likely to vary significantly (for example, tensile or compression strength or abrasion resistance is only of secondary concern and usually linked to other parameters within polyurethanes). Typical pricing on rigid polyurethanes matching our needs should be in the $15-$30 range per kg.

Worldwide, Huntsman has a pretty impressive range of rigid polyurethane resins; so does Axson. In the States, a very interesting range of compositions is available from Innovative Polymers (once more, a shameless plug for Walco Materials goes here), and a handful of custom formulations is sold by Freeman Mfg & Supply. There is also a number of smaller or more specialized shops, such as Smooth-On, but they usually have a less interesting selection, or exploitative pricing. In the United Kingdom, Mould Life predictably carries a broad selection of rigid resins, too.

Although they are priced very competetively, it is usually best to stay clear of resins designated as "fast-cast" or something along these lines; such compositions are typically meant as a backing for tool dies and molds, for making quick visual mocks, and other conceptual prototypes - but they are a very sloppy material for engineering purposes due to inferior mechanical characteristics.

In the States, my top recommendation would be Innovative Polymers IE-3075, which is a hard (80 Shore D), rigid and durable (120 MPa flxural strength, 2.9 GPa flexural modulus) resin with a neutral translucent color and a reasonably long pot life of 8 minutes; it is also fairly inexpensive compared to most other alternatives, at slightly over $12 per liter or so. Huntsman offers several vaguely comparable resins on the North American market - RenCast 6492, 6470, 6419 - but they are usually not in continuous stock, so minimum order sizes, long lead times, and asinine pricing all apply. There is also RenCast 6491, which is easier to get - but it's deceptively hard to pigment due to its strongly masking color, and has an uncomfortably short pot life.

In Europe, the situation is different - although Innovative Polymers do not have any resellers that I know of, Huntsman's RenPIM 5219, also sold as RenCast 5146, is pretty close to the IPI product, and fairly cheap. It has a hardness around 85 Shore D, ~100 MPa flexural strength, modulus of ~3 GPa, 20 minutes pot life, and a neutral white color that is easy to dye as desired.

RenCast 6491, 5146 / 5219, as well as IPI IE-3075, are all very moisture-sensitive, and benefit from the addition of molecular sieves to the mix (see later for an explanation what it is, and where to find some). Their cure profile is otherwise excellent: great surface cure, long low-viscosity stage, good tolerance for heat-accelerated curing.

One of the aforementioned products should fulfill most of your part manufacturing needs, but there are several other resins worthy a mention. For example, you might want to have a look at Inovative Polymers TP-4020. It is roughly comparable to IE-3075 on many counts, if a bit more brittle (flexural stength 110 MPa) - but because of a composite filler, it has an impressive flexural modulus of around 6 GPa, resulting in unmatched rigidity; and because of a polyurea chemistry, also a very high temperature resistance. It is especially useful for lightweight frames, precision gears, hot-running motor mounts, and so forth. It costs about $40 per liter, so it's not exactly cheap in comparison, though.

Other resins worth exploring are transparent compositions; they cost up to twice as much as their translucent or opaque friends, but they have an array of obvious, decorative or quasi-decorative applications; nothing beats a transparent gearbox. My favorite transparent resin is Innovative Polymers OC-7086 - excellent mechanical properties (80 Shore D, 110 MPa flexural strength, 2.4 GPa flex mod), nice cure profile, no mercury or other surprises, about $30 a gallon, slightly under 20 minutes pot life. Axson PC 521 is comparable, but mercury-catalyzed.

7.4. Alternative plastics: epoxies and polyesters

Polyurethanes aside, there are some other rigid plastics that can be reasonably cast in home workshops. I find them to be less useful in hobbyist engineering applications, and I do not think it makes sense to stock up on them ahead of the time, unless a very specific need exists - but nevertheless, they are worth a mention.

Epoxy resins are a class polymerizing resins commonly used in industrial applications. Although some significant variations between offered compositions occur, compared to polyurethanes, epoxies are generally cheaper, harder, stiffer, and less affected by contaminants than polyurethanes; but they also exhibit greater shrinkage and curing exotherm, are more brittle, less resistant to elevated temperatures, and more viscuous once catalyzed.

For most part, polyurethanes perform just as good or better than epoxies and are easier to work with; but epoxies can offer better compressive strength and wear resistance for large parts such as molds or sheet material forming tools. Epoxy putties and thixotropic pastes are also commonly used for various repairs - including patching prototyping boards and molds - because unlike polyurethanes, they are not sensitive to moisture and can be worked without any particular precautions. There are some vague concerns around one of the chemicals used as a feedstock for epoxy resins (chiefly bisphenol A), so be sure to read the safety notes provided later in this document.

The other super-low-cost alternative to polyurethanes are isophthalic polyester resins. Polyesters are extremely hard (40-45 on Barcol impressor, out of range on Shore D), rigid, and pretty brittle (flexural strength 50-80 MPa) - and most importantly, often transparent and crystal clear. They are a good, low-viscosity alternative for making decorative transparent parts and jewelry; sadly, their brittleness excludes them for some mechanical uses unless the resin is reinforced with a laminate. Their high shrinkage (5-10% is not uncommon!) makes them nearly useless for precision work, too. Polyester putties, on the other hand, are pretty useful for quick repairs, primarily because of their rapid cure. Keep in mind that styrene used in polyester resins is very volatile, flammable, and has a strong, penetrating odor.

Anyway... various epoxies and polyester resins and the likes can be obtained from multiple local manufacturers; Freeman Mfg & Supply is one of the options if you want to take this route.

7.5. Adding colors to resins

Adding color to silicones, polyurethanes, epoxies, and polyesters is a fairly straightforward task, but there are several considerations that make it a bad idea to just get watercolors from the supermarket, or paint colorants from the hardware store. Many resins are sensitive to, or reactive with, substances that cause no problems in more down-to-earth applications. For example, isocyanates in polyurethane react with water to product polyurea and carbon dioxide bubbles; and also happen to react with certain solvents, surfactants, and inorganic dyes. Polyaddition cure silicones fail to polymerize, or polymerize prematurely, in the presence of some common solvents, surfactants, and metal ions. Finally, polyester catalysts oxidize some dyes, possibly turning reds into yellows, or causing similar surprises.

Since you probably do not want to go through too much trial and error, do not want to have separate sets of pricey pigments for each type of a resin, and you likely want to be able to achieve punchy, lively colors - my recommendation would be to shop for a proper selection of dry, synthetic organic pigments from a specialized source. For example, Kremer Pigments, an excellent and affordable manufacturer easily available in the States and most of Europe, carries a selection of easy-to-mix studio pigments. Unfortunately, Kremer's products are much more expensive in the States than in Europe, as they are imported from Germany - but I don't know of any other online store with a comparable selection.

They also have a range of similarly non-reactive, extremely bright, daylight fluorescent pigments in a resin lattice, for somewhat more expensive, but absolutely stunning colors (this is because these substances not only reflect light, but also emit specific wavelengths when excited by absorbed light in high-energy parts of the spectrum).

If you intend to work with translucent or transparent resins, you will also need soluble dyes. Although many organic pigments already dissolve in polyurethane resins, resulting colors might be quite off from what they are in opaque materials (and likewise, soluble dyes may produce brilliant colors in transparent resins, and really poor hues in opaque ones). Instead of trying your luck, you might pursue two other options: one is to buy raw dyes, such as ORASOL (also available from Kremer), and dissolve them as needed. The upside is that you pay less, and the downside is, you get a less sophisticated selection that might require some mixing to achieve certain shades. The other option is to get a set of pre-made dye solutions, such as the underwhelming Axson COLORKIT, or much better sets offered by Eager Plastics (US), ABL Stevens (UK), and many other places. These pre-made solutions will be almost certainly incompatible with polyaddition cure silicones, but should work OK with polycondensation ones.

Finally, once you are settled with the basic palette, it makes sense to look around: there are some stunning phosphorescent, pearlescent, glitters, and "raw" organic and inorganic pigments that may yield stunning finishes or simulate more expensive materials; Kremer is one of your options here, but a better selection is available from Paint with Pearl.

Some general pigment selection tips: My recommended choice of pigments is as follows: As noted, mixing some dry pigments is an art by itself. The best way to go is to first add just several drops of isocyanate (or isocyanate-compatible solvent / surfactant), an amount comparable with the amount of pigment to be dispersed, and then stir the contents very thoroughly to ensure that all pigment is wettened with no clumping present (it is very difficult to hunt clumped particles once all the resin is poured in). You can then add the remaining isocyanate, leave it covered for several minutes to let any residual moisture from the pigment react with the resin, and only then pour in polyol. In particularly difficult cases, an isocyanate-compatible wetting agent such as Triton X-100 or Surfynol 61 might come handy, and so does a stirrer.

You can also ignore all of the above and buy specialty coloring pastes and dyes from the manufacturer of the resin you intend to use. You will pay more, the colors are hit-and-miss (for example, Axson's "yellow" is greenish, Huntsman's is reddish; Axson's "red" is slightly violet, Huntsman's "red" is blood red), their lightfastedness unknown, and selection limited - but it will be more convenient than working with dry pigments.

Regardless of which way you decide to go, you might have a need to employ your dry pigments or dyes to touch up or paint over sections of cast parts, or to apply certain surface finishes (glitter?) to the material. One of the best ways to do so is to use a clear coat lacquer. You can get them at most automotive stores, etc.

7.6. Making plastics look like metal

Plastics filled with metallic / pearlescent pigments or flakes look very cool - but they do not look like "proper" metals, unless you count anodized aluminium as one. A clever way to make plastics look more like the real thing is to fill them generously with fine metal powders (iron and copper work particularly well). This will initially give them a disappointing look (black for iron, rusty for copper), but if you then polish their surface with an absrasive, a shiny metallic aspect is soon achieved.

What is less obvious is that it's fairly easy to cover polyurethanes, epoxies, and polyesters with thin layers of actual metal. The usual, hobbyist-friendly process goes as follows: first thoroughly clean the surface of the part to be coated (usually with a solvent or a strong acid), then sensitize it with a solution of stannous chloride (SnCl2), and finally perform electroless plating with copper, nickel, or silver salts (Tollens reaction). Once a conductive layer is established, the part can be further electroplated if so desired (to skip the electroless plating step, conductive paints may also be used - example).

I will not be providing any detailed instructions in this document, but particularly if you are thinking of doing any jewelry work, it might be worth looking into. Electroless silvering is particularly hassle-free, requiring only distilled water, stannous chloride, ammonium hydroxide, sodium hydroxide, silver nitrate, and some glucose. Ready-made nickel, cobalt, and tin kits are available e.g. from Caswell Plating, too - but boy, they can be expensive.

7.7. Creating reinforced plastics

Where necessary, key physical properties of plastic resins can be greatly improved by constructing composite materials with substances such as glass, metal, carbon, or fabric.

One of the most common methods of producing such composites is laying layers of fine synthetic fabric in a resin to improve tensile and flexural strength and impact resistance of the final part; sometimes, for simplicity, shredded strands are used instead of a coherent fabric, resulting in worse properties, but taking away the need to carefully trim and lay out the material. Typical materials used in such composites are thin, tightly woven fiberglass, carbon fibers, or aramid fibers (e.g., Kevlar). Polyurethane, epoxy, and polyester resins can be reinforced alike. Silicone is more difficult, as it would not wet the fabric unless it is pre-soaked in a suitable non-polar solvent first.

Sheets and tapes of fabric can be readily purchased from a number of regional resellers, with various thickness and fiber layout; one of best known manufacturers is Hexcel, with a network of distributors worldwide. To get an idea of pricing and selection available, you can visit US Composites too. Thin bidirectional carbon fabric under 175 g/cm³ is probably most useful in rigid, precision applications. Polyamide and aramid cloth is more useful for reinforcing elastic parts (e.g., belts, tires).

Another class of composites are "syntactic foams" - resins filled with microscopic hollow spheres, such as glass-based Scotchlite S 22 (bubble diameter around 50 µm). These bubbles may be introduced into resins in proportions up to around 3:1. Such a syntactic foam would not have better flexural or tensile properties - but is extremely lightweight, and has an excellent compressive strength, abrasion resistance, and surface aspect, compared to traditional foamed plastics.

Lastly, another curious type of composite material is natural wood, carefully dried and then soaked with a plastic resin. Doing so is a lengthy process that requires the wood to be completely dry, and the resin to be mixed with a proper penetrating agent, then forced into the material by using pressure differences (e.g., with a vacuum pump or a pressure chamber). Such composites retain the appearance of the original wood, but gain high stability, weather, and scratch resistance.

8. A word on solvents

Working on plastics and paints often requires the ability to dilute or remove intermediates from various surfaces. My recommendation would be to keep reasonably small quantities following solvents handy for all work: You might have some specific uses for white spirit, xylene / ethylbenzene mixtures, etc - particularly where lower volatility and longer drying times are required; but nothing to stock on. Also, note that unlike some other plastics, fully cured polyurethanes and epoxies are nearly impossible to dissolve with common solvents - so play it safe.

9. Release agents

Mold releases are an important part of the molding process, serving as a barrier to prevent adhesion or chemical interactions between a previously machined or cast mold, and the liquid resin poured into it. Mold releases are optional for silicone-polyurethane combinations, as the two materials do not stick or react with each other significantly (but a thin layer of a release agent might still make mold removal easier, prolong its life, and improve surface aspect of the final part); they are essential with silicone-silicone, polyurethane-polyurethane, and all epoxy and polyester processes, however.

There is a very broad selection of release agents for various purposes, including systems that form peelable films (polyvinyl alcohol, latex), hard polishable shells (wax, certain plastic-based systems), temporary dry powder layers (PTFE, zinc stearate), or non-reactive liquids (silicone and mineral oils, plus many mysterious proprietary formulations). Each of these options is usually available with various viscosities (from water-like for applying to complex molds, to pastes for maximum efficiency with simple shapes), solvent mediums (for compatibility with different materials), etc.

Of all these types, peelable films and dry powders are not particularly well suited for the processes we are interested in (simply by the virtue of being fragile and hard to apply), but beyond this, the exact choice is just a matter of personal preference. For preparing machined masters before casting silicone molds, I would recommend a low-viscosity release such as wax-based AdTech MR-1 mold release (US only, works best in a 2:1 dilution with VM&P naphtha), or Huntsman RenLease QZ5111 (EU only, perfect as-is). Stoner E302 is a good spray-on, easily removable, but non-polishable option where a satin finish is acceptable; and Stoner A324 can be used to create thick, high luster coats with some practice. Lastly, paste waxes such as Trewax can be used to obtain final, robust shine for simple molds; epoxy surface coats such as AdTech ES-201-PC also work for this purpose when dimensional accuracy is not critical, but work best with a paint gun or an airbrush.

For preparing silicone molds to cast final parts, you may find silicone-based Stoner M804 to offer superior performance - it's definitely my favorite; but E302 can be used as well (A324, not so much).

As it is probably clear by now, mold releases are available under a wide array of brands - Huntsman, Axson, Freeman, Krylon, Stoner, Partall, CASS / Adtech, etc. Stoner has possibly the most impressive selection of and superb customer service (including free shipping on bulk purchases!), but unfortunately, some of their products are not listed on the Web - you might need to contact their customer service to get a quote and place an order instead.

10. Casting tools and other workshop stuff

All right, enough with the chemicals for a moment. I assume that you already own, or know how to set up, a basic workshop for electronic and fine mechanical work. The expected equipment includes: I also assume a basic understanding how to use these tools efficiently and safely. If this is not the case, stop now, look up additional information elsewhere, get the missing equipment, and practice a bit.

Some of the more exotic tools and supplies you might want to purchase to make casting and machining easier include: And now, some less obvious tricks of trade: As you probably noticed, I advocate the use of single-use syringes, containers, and other equipment. Not everything needs to be used only once and then thrown away, to be sure. Some basic rules are as follows:

11. Safety and health

Last but not least, some important (but non-authoritative) advice on safety and health considerations for milling and casting processes.

A quick disclaimer: we are talking power tools and reactive chemicals, not fuzzy bunnies. It is your responsibility to read and follow manufacturer's guidelines, familiarize yourself with appropriate datasheets, and follow proper operating procedures. If you blindly rely on advice from a random guy on the Internet, you are asking for trouble.

Finally, no matter how careful you are, things may still unexpectedly explode in your face in a fiery fireball, cut your left toe off, and run away with your wife. Accidents happen, discoveries of new health and safety considerations are being made, and there is an inherent risk you simply must accept and cannot delegate. If you do not want to, you need to find a different hobby.

11.1. Power tool safety

In general, small CNC mills are fairly safe compared to other power tools: you, your kids, and fellow animals, are probably not going to be badly hurt in an accident, but common sense still needs to be observed.

Unlike with hand-operated tools, there is absolutely no reason to get intimate with the machine while it is operating, so do not - and advise others to stay clear of the device, too. The most significant risk does not actually come from accidental contact with the side of a rotating cutter itself (although it is sharp, it's not constructed in a manner that would enable it to grab your limbs and rip through them on slightest contact, like a saw blade would). The primary concern is having your hand pinned by a moving table or a descending cutting head, or having your loose clothing or hair tangled up and pulled in by the spindle or a rotary axis.

Even then, small benchtop units usually do not have the power to cause horrific and life-threatening injuries - but do not be tempted to bet on this. Stay alert, keep clear of the machine when it's operating, do not wear loose clothing. Do not operate this or any other power tool if incapacitated, and really, use your brain.

Another important concept is eye protection. Rough milling of metals and brittle plastics may eject sharp swarf in random directions. In addition, end mills may shatter when abused, sending sharp bits of carbide flying around. The odds of this debris hitting your eyes are low, but it is probably not a risk worth taking. Since you will be tempted to observe the progress of cutting (don't deny it), it is best to use protective eye wear (there are some lighweight and reasonably stylish options available these days - example), or at least put a makeshift acrylic glass or polycarbonate screen in front of your machine.

11.2. Noise considerations

Benchtop milling machines are relatively quiet themselves - when operating at highest speeds, the noise usually stays below 65 dB (A) or so, less than a typical hair dryer, and the pitch of noise they produce is not particularly unpleasant. When plowing through the workpiece, however, rotating end mill may produce louder and more annoying noises that might prove to be a nuisance to people in the room, or - when milling in the middle of a night - to your across-the-wall neighbor.

Some materials will be particularly noisy when machined (metals and very rigid and hard plastics can get to 80-100 dB (A)), while other materials will be almost always completely silent (waxes, lightweight rigid foams, etc). For a particular material, the loudness and pitch may still vary quite significantly, depending on factors such as spindle rotation speed, end mill geometry (diameter, profile, number of flutes), cutting depth, feed rate, workpiece thickness in a particular location, or milling direction.

You should put the machine in a room that can be temporarily vacated for a couple of hours, with doors closed, whenever you want to do some milling. It might make sense to get some ear protection, too, if you want to check on the progress every once in a while (and certainly if you want to sit nearby at all times).

11.3. Dust considerations

Milling machines do not emit toxic fumes and do not use harmful chemicals as such (assuming you do not use coolants). That said, certain types of dusts given off during sanding, sandblasting, polishing, sawing, grinding, milling, and many similar operations, may pose a respiratory hazard. This problem is not specific to CNC devices - and in fact, would be far more pronounced when using a jigsaw or a sander - but a warning is in order.

Many materials do not give off appreciable amounts of volatile dust when milled at normal speeds, producing heavier shavings instead; and in most cases, when fine airborne particles are produced, they can be classified as nuisance dust - such as is the case for powdered acrylic glass or polyurethane. These particles shouldn't be inhaled in excessive quantities, as they may, in extreme cases, lead to generic, chronic respiratory problems - but there are no specific, known adverse effects unique to such materials. It goes without saying that inhaling lots of any type of dust for too long is bad for your lungs.

In other words, it is a good idea to ensure proper ventilation, vacuum the workplace when done - but there is compelling reason to panic. If in doubt, or if you have preexisting respiratory problems, you might want to talk to a doctor.

Now, there are some types of dust that are known to be more dangerous, and these you need to watch out for. Heavy exposure to certain types of silica dust (glass, sand, quartz) is known to lead to silicosis, a serious, sneaky, and incurable chronic disease marked by particularly nasty scarring and lesions of lungs, sometimes leading to cancer; pretty much the same goes for asbestos and several other minerals.

You are unlikely to be milling rocks or glass, but note that mineral fillers are used in some abrasion-resistant plastics, as well as certain inorganic pigments, may fall into this group; quartz may be also present in residual quantities in zeolite, hollow glass spheres, etc. Some sources argue that dusts produced when cutting fiberglass may be similarly dangerous, although the evidence there is limited, and subject to debate. The current consensus seems to be that crystalline silica particles of under 7-10 µm pose a significant threat. But you seldom have the luxury of knowing what size you are dealing with.

Be sure to read material safety datasheets for any materials you want to use, and avoid prolonged and extensive cutting of mystery plastics of unknown composition (use a proper dust mask and ensure ventilation when doing so). All the materials I recommend in this guide as CNC feedstock should be safe in this regard.

There are some other respiratory risks that you should probably be aware of. Heavy, long-term exposures to wood and carbon dusts were recently linked to a somewhat higher occurrence of certain respiratory cancers in workers; this may or may not apply to carbon fibers as well, although the risk in hobby work is likely negligible. Similar concerns are being also raised for titanium dioxide (white pigment). Also, significant exposure to dust of certain metals or their compounds may eventually cause metal poisoning, because of surprisingly efficient absorption through the lungs.

Bottom line is, you need to know what you are milling, sanding, or handling in powder form; and read up on the potential health effects and act responsibly. You do not have to overreact - chances are, your dust exposure when just taking a walking down a busy street is higher by several orders of magnitude - but use common sense, and consider basic respiratory protection when appropriate.

11.4. Dealing with chemicals

With dedicated prototyping formulations, the chemistry involved in plastic casting is relatively safe if used properly, but still far from beneficial to your health. Acute exposure to vapors as a result of a major spill, aerosolization, or heating up of uncured material, is almost always dangerous. Ditto for accidental ingestion. Chronic exposure because of leaky containers, unnoticed spills, or contaminated clothing, may have adverse health effects in some cases, too. Very high temperatures or random mixing with other household substances may (and almost certainly will) lead to harmful or violent decomposition, polymerization, or other spectacular, exothermic reactions.

Now, there is no reason to panic - the list of health and safety considerations for such familiar substances as instant glues, drain cleaners, bleaches, or limescale and rust removers are often just as scary, and serious exposure incidents are more likely. Still, you probably do not want to needlessly add yet another risk to the list - so it makes sense to observe some basic precautions.

Also note that a constantly growing list of chemicals is suspected or known to cause developmental toxicity, even if they otherwise seem to be safe for adults. Because of this, it is prudent for pregnant and breasteeding women, and infants, to avoid unnecessary exposure to any chemical agents, including solvents, casting resins, plasticizers, organometal catalysts, etc.

When working with casting resins, be sure to organize your workplace properly; ensure sufficient ventilation, clean up spills promptly and thoroughly, throw away irreversibly contaminated clothes and household items, and always close the containers tight immediately after use. Eye protection is advised, as many of the substances are irritant if splashed. Gloves are a good idea too, particularly if you have sensitive skin (though severe reactions are relatively rare upon short exposure).

Keep all chemistry out of reach of children and away from foodstuffs, incompatible materials, and sources of heat - and inspect the containers regularly for damage or other worrying symptoms. Familiarize yourself with Material Safety Datasheets (MSDS) published by the manufacturer of each formulation (they are commonly posted on web sites, and if not, can be requested by e-mail): even a resin of a typically harmless kind might contain more dangerous modifiers, but if so, these would need to be disclosed in said datasheets.

Some chemicals, such as polyester resins and wax demolding agents, are highly flammable (but most silicones or polyurethane resins are not). Store these chemicals away from sources of fire and other flammable materials, and get a small fire extinguisher to store in the workshop, too (it costs next to nothing, so why take the risk?).

Polymerization of polyurethanes, epoxies, and polyesters is exothermic; and the shorter the pot life, the hotter the resin will get. With fast-cure resins (pot life under 5 minutes), it is quite possible to create a runaway reaction that would result in the resin boiling or melting the container it is in. To avoid this, do not exceed manufacturer's recommendations on the maximum volume of a part, and do not heat up the resin while it's still liquid.

11.4.1. Silicone rubbers

Silicone casting uses partly polymerized siloxanes as the primary component of a resin. In most mold-making compositions, the resin is largely inert, does not appreciably evaporate, usually has no specific health considerations, and no particular smell. The resin is sticky and not water-soluble, so if you are clumsy, it is easy to stain clothing and furniture made of porous materials (non-cured spills can be cleaned up with non-polar solvents such as naphtha, though).

As a catalyst, condensation cure resins use comparatively small amounts of an organic tin compound, often dibutyltin dilaurate. This chemical is somewhat irritating, and upon ingestion or heavy exposure to vapors, may cause systemic toxicity. If using a condensation cure rubber, observe basic precautions to avoid excessive inhalation and other exposure (cured rubber might be giving away trace amounts of the chemical for some time after cure, too, so do not chew on it while watching TV). Dibutyltin dilaurate is also not very environmentally friendly, so do not dump significant quantities of it into household garbage - react it with siloxanes to form a rubber instead.

On the other hand, addition cure resins rely on platinum catalysts, and all components are almost always very safe to handle and odorless; in fact, cured product is often explicitly approved for contact with food (for example as a mold for chocolate bars and other candy) or certain medical uses.

11.4.2. Polyurethanes

Polyurethane casting commonly involves two base components, used in comparable amounts: a complex sugar alcohol (polyol), typically inert and with very modest toxicity; and isocyanate, a somewhat more hairy beast. This composition is not necessarily true for all products on the market, though: some specialty resins may be polyureas or polyurethane-polyurea hybrids, where polyols are replaced or blended with complex amines. Whether the result is called a polyurethane or a polyurea depends on the manufacturer; but you can tell by the telltale brownish hue of the non-isocyanate component that amines are present, plus a slightly musty or fishy smell. Regardless of the core composition, a very small amount of an amine or organometal catalyst that accelerates the reaction (e.g., DABCO, DEHA, bismuth-, zinc-, or tin-based compounds), as well as variable amounts of chain modifiers, surfactants, or inert fillers to alter certain physical properties of the cured material, may also be present.

Isocyanates are a health hazard because they are acutely irritating; inhaling aerosols or vapors can be dangerous, so can be getting them in your eyes. When used in prototyping solutions, they are often partly polymerized to render them largely harmless - but doing so increases viscosity, and so, the monomer usually still constitutes some percentage of the solution. You can tell by looking at the material safety datasheet: the prepolymer is often not listed at all, but percentages for all monomeric isocyanates will necessarily be.

In a vast majority of resins, the monomer used is methylene diphenyl diisocyanate (MDI), the least harmfull of the bunch: a solid with a negligible evaporation rate in normal conditions (about a million times lower than water). In transparent, elastic, and other specialty resins, other members of the isocyanate family may be present, however: methylene bis(4-cyclohexylisocyanate) (known as HMDI, DMDI, and under several other names), isophorone diisocyanate (IPDI), toluene diisocyanate (TDI), hexamethylene diisocyanate (HDI), or several more exotic options. HMDI and IPDI are generally OK, although more risky than MDI; TDI and HDI should be avoided if possible, due to higher volatility and toxicity.

As far as I know, MDI, HMDI, and IPDI do not exhibit any pronounced long-term toxicity: the primary health is that, as mentioned, they tend to be irritant. They are also known to cause sensitization in a minority of people, particularly following a single sudden and excessive exposure, or years of high-level exposures in industry workers. Sensitized individuals will exhibit allergy-like skin or respiratory response on future contact with isocyanates, even at very low concentrations. Sensitization is a significant concern for spray applications of polyurethane coatings in the automotive industry, and in other large-scale operations; but should be much less likely in hobbyist casting work. Significant exposure to vapors may still occur if the resin is spilled in significant quantities, accidentally aerosolized, heated up, deliberately inhaled, or otherwise mishandled - but low volatility of the aforementioned three isocyanates makes other modes of exposure less likely.

In any case: do not sniff containers, do not work with large quantities of resin in confined spaces with no ventilation, and avoid any procedures that make it likely for spills to occur (tipping containers, leaving them open while you reach for something else, etc). If you notice a shortness of breath or other unusual respiratory symptoms within hours after being exposed to isocyanates, you might be among the unlucky few prone to this condition. In such a case, it may be important to seek medical assistance and perhaps avoid further exposure.

What else? Ah, isocyanates are fairly reactive, and may polymerize or decompose in contact with many household substances, water and alcohols included. They are not a particularly unstable chemical, to be sure, but some caution is advised. If a significant quantity of an incompatible substance is introduced into a tightly closed container, it might lead to a disaster. On the upside, because of their tendency to react with water to form stable and inert polyureas, minor spills do not pose a serious long-term threat, and have no pronounced environmental burden.

Moving on to the other component: polyols are largely inert, and seldom appreciably harmful - you shouldn't be drinking them, but no special precautions are necessary; if disposed of, they are expected to readily biodegrade, too. Aromatic amines used along with or instead of polyols in polyurea compositions are a more complicated topic. Most of them have low acute toxicity, but several of the variants used in the past were deemed likely carcinogenic: most notably, 4,4-methylenedianiline (MDA) and 4,4'-methylenebis(2-chloroaniline) (MBOCA or MOCA). New substitutes, such as dimethylsulphidetoluene diamine (DMTDA), appear to be safer - but are closely related and fairly new, so some questions remain. Google around.

In most cases, these two components, plus tiny amounts of pretty safe catalysts, surfactants, and desiccants, are all there is to a resin; but there are at least two exceptions to keep an eye on: These specific considerations aside, cured polyurethanes are one of the safer and least controversial plastics out there: they do not routinely contain any dangerous plasticizers or catalysts, any eventual unreacted isocyanates degrade or react with water quickly, and unreacted polyols pose little or no threat. Like most plastics (and organic materials in general), polyurethanes release a fair amount of toxic substances during thermal decomposition, so try to resist the urge to burn them if at all possible.

11.4.3. Epoxies

The primary components of many prototyping resins are various partly polymerized diglicidyl ether compounds, which are somewhat corrosive, very sticky, and otherwise messy, but should not pose an immediate health hazard during normal use. There are some marked differences between products on the market, however, so be sure to check manufacturer's documentation first; in particular, the list of possible plasticizers and modifiers that can be present in epoxy resins is even longer than for polyurethanes.

Feedstock for many epoxies includes bisphenol A; the product you will be using will still contain somewhere between 1 and 50% of the raw thing, depending on the formulation. The substance has a relatively low acute toxicity, but is long suspected to have potential chronic exposure effects, even in very small amounts - as it can disrupt certain hormonal processes. The danger BPA poses to humans is not really clear - on one hand, if there were pronounced effects, we would probably have noticed by now, given the ubiquitous use of epoxy resins and polycarbonate (a yet another bisphenol A polymer); on the other, animal studies give some troubling results. Regardless of the merit of these concerns, the controversy is here, and BPA being voluntarily phased out in certain products by some manufacturers, and you may want to limit your exposure, too.

The important difference is that while only a minority of polyurethanes may contain controversial additives such as DBP or organomercury catalysts, and it's perfectly possible to avoid these formulations - with epoxy resins, there is no way to avoid BPA altogether.

Bisphenol A aside, resin hardeners use a wide variety of polyamine compounds, such as diethylenetriamine (DETA). These hardeners are corrosive and irritating, and should be handled with care. Cases of sensitization, similar to that to isocyanates, were observed, too. Otherwise, toxicity seems to be modest - but check with the manufacturer, and use common sense.

Unlike polyurethanes, unreacted epoxy components are not environmentally friendly if disposed of inappropriately: they may contaminate ground waters; on the upside, they biodegrade fairly soon when exposed to oxygen and sunlight. But regardless of this, be sure to polymerize any significant leftovers prior to disposal.

11.4.4. Polyester resins

Polyester resins are based chiefly on styrene. This compound is very volatile, extremely flammable, and should not be inhaled excessively, as it seems to act as a CNS depressant past a certain point. Because of high evaporation speed, dangerous concentrations can be reached in closed spaces without a considerable effort. It takes some dedication to ignore the strong and overpowering smell of styrene long enough, but eventually, you get used to it - and get all the brain damage of glue sniffing with none the thrill.

Perhaps more importantly, styrene is suspected by some to be a possible carcinogen. Few in vitro and animal studies linked high exposure to styrene to a visibly increased occurrence of several cancers. Human studies of sizable populations of styrene industry workers, many of which were exposed to very high levels of styrene for decades, found no conclusive evidence in practice; many scientists seem to believe that such a link is not very likely - but the matter is not settled. Animal studies were enough for some agencies to classify styrene as a probable human carcinogen, but not enough for others.

Polyesters are usually cured with minutiae amounts of organic peroxides, such as methyl ethyl ketone peroxide - which itself is a high explosive, though it is stabilized in such formulations and poses no immediate threat. The catalyst can be also expected to be corrosive and somewhat irritant. Other notable modifiers are less commonly seen, as most polyesters are designed just to be hard, brittle, and as cheap as possible.

The environmental footprint of styrene is comparable to that of epoxy resins - it is a short-lived but problematic pollutant, and should be disposed of with care.

The harmful effects of styrene does not necessarily mean you should avoid polyesters at all costs - but given that the alternatives are more user-friendly and perform just as well, it should in all likelihood not be your primary resin.

Cured polyester resins should be safe. Like polystyrene, they may seep trace amounts of styrene into the environment. There is no compelling scientific evidence that this could be harmful (whereas a quasi-plausible, if vague, mechanism of action is postulated for BPA and DBP in the same situation). This did not stop several advocacy groups from calling to have styrogoam and polystyrene cups banned, but this is probably without merit.

11.4.5. Pigments and dyes

There is a great selection of pigments and dyes available from a large number of manufacturers. A vast majority of modern synthetic pigments is - to my best knowledge - not appreciably toxic, and not leaching out of materials. In particular, Kremer studio pigments, fluorescent pigments, and ORASOL dyes, seem to be a safe bet.

That said, not all is roses. Key risk factors to look out for:

It is particularly important to avoid harmful pigments when spraying coats with an airbrush or a paint gun. For such applications, stick religiously to reasonably safe compositions.

In addition, not every pigment is guaranteed to be compatible with every possible resin; be sure to perform initial tests on a small quantity of material, and immediately contain and discard the sample, then cease to use the dye, if an unexpected reaction is evident (through color change, premature polymerization, inhibited polymerization, foaming, smoke, etc).

11.4.7. Solvents, glues, demolding agents

All these substances come with own sets of safety warnings. You should read them. Unless specified otherwise, assume every solvent to be highly flammable (so do not store large quantities in any single place, do not use them near sources of fire, and preferably get a fire extinguisher for your workshop - and be extremely careful when spraying them on). They are also usually harmful if inhaled excessively (so ensure proper ventilation, do not inhale, and always wear a proper respirator during major spray applications), irritant to eyes and to sensitive skin, and - in som cases - dangerous to aquatic environments (don't flush them down the drain).

Some solvents and synthetic waxes should not be overheated, even in residual quantities; fire hazards aside, they can also undergo thermal decomposition to acrolein - a toxic compound with a very unpleasant, piercing smell akin to burnt grease. This decomposition may occur in well-sealed ovens even at fairly low temperature presets, e.g. 100° C, as the rapidly evaporating substance would come into contact with a hot heating element operating at a higher temperature, then decompose and react with air on the spot. Bottom line is, if you're drying or cleaning a mold, don't push it; and if you notice a choking smell, stop and ventilate the area: It can quite easily make you sick.

11.5. Staying legal

No matter how goofy it sounds, you will need to study regulations to make sure that you are permitted to own the equipment and chemicals you want, and that any contaminated refuse is disposed of properly. In many places, you are not expected to dispose of any broadly defined hazardous waste with your household garbage - but only some cities offer sensible alternatives. If your city actually runs a free-of-charge hazardous waste recycling program, you should use it to drop off any half-empty cans of unreacted resins, significant amounts of solvents, etc.

Read up on any local ordinances, as some of them are fairly peculiar, and span from boneheaded zoning laws that flat out ban you from "manufacturing" anything in residential areas, to overreaching anti-drug regulations that require a permit and a thorough home inspection to buy a beaker or a flask (see article). As mentioned, in nine US states, you actually need a prescription to buy syringes - go figure.

If your local laws are sensible or non-existent, use common sense and have fun. If your regulators are overzealous, consider finding other local hobbyists, educators, book authors, and petitioning for change. If you ignore stupid laws, nine out of ten cases, nobody would know or care; but you really do not want to be that one unlucky guy who somehow runs into trouble.

12. What next?

Well, this concludes this part of the guide. You should now have a good picture on how to set up a machine shop at home, what materials to use, and how to work with them safely.

Volume II, outlining some practical CAD / CAM workflows and part design tips, as well as a primer on nuts, bolts, dowel pins, and other prefabricated supplies essential to robot work, is coming soon; in the meantime, feel free to bug the author with any any specific questions, suggestions, concerns, flames, etc.